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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = 'a09a6716d75a67dc371f4874c25590d4fa8991fec22b73c09d09a4237046b351' 
  AND token = '9TZTel+12xvJFQG1ZBaNWXzfpEfHJtx2IYD9iBUMYJA=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00015

JSON explain

{
  "query_block": {
    "select_id": 1,
    "table": {
      "message": "Impossible WHERE noticed after reading const tables"
    }
  }
}